Published in: 20th Iranian Chemical Congress
COI code: IRANCC20_044
Paper Language: English
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Authors TiO2 nanoparticles supported on the Fe3O4/GO nanocomposite: a novel magnetic nanocatalyst for the synthesis of 2- AminothiazolesZinat Gordi - Department of Chemistry, Payame Noor University, Tehran, Iran
Ali Rajaee - Department of Chemistry, Payame Noor University, Tehran, Iran
Ebrahim Fooladi - Department of Food Nanotechnology, Research Institute of Food Science and Technology (RIFST), Mashhad, Iran
Abstract:2-aminothiazoles are very important heterocyclic compounds in medicinal chemistry and applied as a ligand in estrogen receptor . In the recent years, application of modified magnetic nanoparticle (Fe3O4) as a reusable and highly stable magnetic nanoparticle has attracted much attention in 2-aminothiazole synthesis . Among many materials, graphene and its derivatives are considered potential materials for the immobilization of nanoparticles. In the present study, Fe3O4/GO/TiO2 nanocomposite was prepared by a sol-gel method for titania coating on Fe3O4/GO. The Fe3O4/GO/TiO2 composite particles were characterized by FT-IR and TEM. In this reaction thiourea was reacted with various α-bromo Acetophenones in the presence of (Fe3O4/GO/TiO2) catalyst affording the desired 2-aminothiazoles in high yields. In conclusion, we have successfully demonstrate for the first time that Fe3O4/GO/TiO2 composite could be used as an efficient solid recyclable magnetic nanocatalyst for convenient synthesis of 2-aminothiazole derivatives under mild conditions. The novelty and synthetic volubility of this method developed the mild reaction conditions, easy experimental procedure, avoiding the use of organic solvents and recovery of the magnetic nanocatalyst.
COI code: IRANCC20_044
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Gordi, Zinat; Ali Rajaee & Ebrahim Fooladi, 2018, TiO2 nanoparticles supported on the Fe3O4/GO nanocomposite: a novel magnetic nanocatalyst for the synthesis of 2- Aminothiazoles, 20th Iranian Chemical Congress, مشهد, دانشگاه فردوسي مشهد, https://www.civilica.com/Paper-IRANCC20-IRANCC20_044.htmlInside the text, wherever referred to or an achievement of this article is mentioned, after mentioning the article, inside the parental, the following specifications are written.
First Time: (Gordi, Zinat; Ali Rajaee & Ebrahim Fooladi, 2018)
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The University/Research Center Information:
Type: Payame Noor University
Paper No.: 47587
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