CIVILICA We Respect the Science
Publisher of Iranian Journals and Conference Proceedings
Paper
title

Activation of C-I Bond by Cycloplatinated(II) Complexes Comprising Tricyclohexylphosphine ligand: Kinetics and Mechanism Investigations

Credit to Download: 0 | Page Numbers 1 | Abstract Views: 129
Year: 2018
COI code: IRANCC20_075
Paper Language: English

How to Download This Paper

For Downloading the Fulltext of CIVILICA papers please visit the orginal Persian Section of website.

Authors Activation of C-I Bond by Cycloplatinated(II) Complexes Comprising Tricyclohexylphosphine ligand: Kinetics and Mechanism Investigations

  Maede Kohi - Department of Chemistry, Institute for Advanced Studies in Basic Sciences (IASBS), Zanjan, 45137-66731, Iran
  Hamid R. Shahsavari - Department of Chemistry, Institute for Advanced Studies in Basic Sciences (IASBS), Zanjan, 45137-66731, Iran
  Sepideh Shabani - Department of Chemistry, Institute for Advanced Studies in Basic Sciences (IASBS), Zanjan, 45137-66731, Iran
  Mohsen Golbon Haghighi - Department of Chemistry, Shahid Beheshti University, Evin, Tehran 19839-69411, Iran

Abstract:

The cycloplatinated(II) complexes incorporating monophosphine ligands, with general formula of [Pt(C^N)(Me)(L)] (L = monophosphine ligand), are normally good choices in order to study of the mechanism of oxidative addition reaction with alkyl halides. [1]. Phosphine ligands are important in the sense that their electronic and steric effects, induced by their substituents, have a considerable impact on the rate constants and activation parameters of such reactions. Electron-withdrawing or electron-donating properties of the substituents and their Tolman cone angle values control the electronic and steric properties of the phosphine ligands, respectively [2]. Herein, we have investigated the kinetic and mechanism of the oxidation reaction of cycloplatinated(II) complexes incorporating tricyclohexylphosphine ligand (PCy3) by MeI (Fig. 1). The new Pt(IV) complexes have been identified by NMR spectroscopy and single crystal X-ray crystallography. The kinetic measurements, supported by the DFT calculations, have been performed using the UV-vis spectroscopy by monitoring the change in the absorbance spectra of Pt(II) complexes

Keywords:

Perma Link

https://www.civilica.com/Paper-IRANCC20-IRANCC20_075.html
COI code: IRANCC20_075

how to cite to this paper:

If you want to refer to this article in your research, you can easily use the following in the resources and references section:
Kohi, Maede; Hamid R. Shahsavari; Sepideh Shabani & Mohsen Golbon Haghighi, 2018, Activation of C-I Bond by Cycloplatinated(II) Complexes Comprising Tricyclohexylphosphine ligand: Kinetics and Mechanism Investigations, 20th Iranian Chemical Congress, مشهد, دانشگاه فردوسي مشهد, https://www.civilica.com/Paper-IRANCC20-IRANCC20_075.htmlInside the text, wherever referred to or an achievement of this article is mentioned, after mentioning the article, inside the parental, the following specifications are written.
First Time: (Kohi, Maede; Hamid R. Shahsavari; Sepideh Shabani & Mohsen Golbon Haghighi, 2018)
Second and more: (Kohi; Shahsavari; Shabani & Golbon Haghighi, 2018)
For a complete overview of how to citation please review the following CIVILICA Guide (Citation)

Scientometrics

The University/Research Center Information:
Type: state university
Paper No.: 331
in University Ranking and Scientometrics the Iranian universities and research centers are evaluated based on scientific papers.

Research Info Management

Export Citation info of this paper to research management softwares

New Related Papers

Iran Scientific Advertisment Netword

Share this paper

WHAT IS COI?

COI is a national code dedicated to all Iranian Conference and Journal Papers. the COI of each paper can be verified online.