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A new ultrasound-assisted approach to the synthesis of metalorganic framework structure derived from the Zn–terephthalic acid–DMF system

Credit to Download: 1 | Page Numbers 5 | Abstract Views: 30
Year: 2019
COI code: IRCCE06_013
Paper Language: English

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Authors A new ultrasound-assisted approach to the synthesis of metalorganic framework structure derived from the Zn–terephthalic acid–DMF system

  Arghavan Abolghasempour - Department of chemistry, Faculty of science, Ferdowsi University of Mashhad, Mashhad, Iran
  Alireza Salimi - Department of chemistry, Faculty of science, Ferdowsi University of Mashhad, Mashhad, Iran
  Ali Nakhaie pour - Department of chemistry, Faculty of science, Ferdowsi University of Mashhad, Mashhad, Iran
  Siroos Rostami - Department of chemistry, Faculty of science, Ferdowsi University of Mashhad, Mashhad, Iran

Abstract:

In this study a Zinc-based metal-organic framework under ultrasound irradiation has been obtained from the rearrangement of Zn-terephthalic acid –dimethyl formamide system to Zn(C8H4O4)(C3H7NO)(H2O). The title compound was characterized by FT-IR and single-crystal X-ray diffraction analyses. The results showed that the structure of the title compound is the known MOF-2(Zn) compound. To investigate the effect of the preparation method of MOF-2 on the gas adsorption process, the adsorption of hydrogen gas at room temperature is examined. The results showed that the total hydrogen storage under these conditions is about 0.26 wt%. This study demonstrated that the different synthesis methods of MOF under various conditions can affect the adsorption properties in these compounds. Indeed, the preparation method along with the design of metal-organic frameworks can be an important issue on the absorption of various types of gases.

Keywords:

Metal-organic framework, Ultrasound, Adsorption, Hydrogen storage

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COI code: IRCCE06_013

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Abolghasempour, Arghavan; Alireza Salimi; Ali Nakhaie pour & Siroos Rostami, 2019, A new ultrasound-assisted approach to the synthesis of metalorganic framework structure derived from the Zn–terephthalic acid–DMF system, 6th International Conference on Chemical and Chemical Engineering, تهران, دبيرخانه دائمي كنفرانس, https://www.civilica.com/Paper-IRCCE06-IRCCE06_013.htmlInside the text, wherever referred to or an achievement of this article is mentioned, after mentioning the article, inside the parental, the following specifications are written.
First Time: (Abolghasempour, Arghavan; Alireza Salimi; Ali Nakhaie pour & Siroos Rostami, 2019)
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Type: state university
Paper No.: 25104
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