Design, Synthesis and Application of a Novel Nanomagnetic Functionalized Acetic Acid as a Catalyst for theSynthesis of Amidoalkyl phenols
Publish place: 26th Iranian Seminar on Organic Chemistry
Publish Year: 1397
نوع سند: مقاله کنفرانسی
زبان: English
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شناسه ملی سند علمی:
ISOC26_116
تاریخ نمایه سازی: 2 شهریور 1398
Abstract:
Activity and reusability of a catalyst should be considered in designing of it. Homogenouscatalysts have higher activity than heterogeneous catalysts, but their separation and recyclingis more difficult than heterogeneous ones. On the other hand, activity of heterogeneous catalystsis low, however their separation and reusability is easy [1]. 1-Amidoalkyl-2-naphtolshave biological importance because they can be converted to 1,3-oxazine [2]. 1,3-Oxazinederivatives have pharmaceutical and biological properties such as anti-tumor, anticonvulsant,antimalarial, analgesic, antibiotic, antianginal, antirheumatic and antihypertensive [3-5].Herein, we wish to introduce [Fe3O4@SiO2@(CH2)3-im-CH2CO2H]Br as a novel nano magneticcatalyst and use it as an efficient and reusable catalyst in the synthesis of amidoalkylphenols under solvent-free condition (Fig. 1).
Authors
Javad Afsar
Department of Organic Chemistry, Faculty of Chemistry, Bu-Ali Sina University, Hamedan ۶۵۱۷۸۳۸۶۸۳, Iran
Mahmoud Zarei
Department of Organic Chemistry, Faculty of Chemistry, Bu-Ali Sina University, Hamedan ۶۵۱۷۸۳۸۶۸۳, Iran
Ardeshir Khazaei
Department of Organic Chemistry, Faculty of Chemistry, Bu-Ali Sina University, Hamedan ۶۵۱۷۸۳۸۶۸۳, Iran
Mohammad Ali Zolfigol
Department of Organic Chemistry, Faculty of Chemistry, Bu-Ali Sina University, Hamedan ۶۵۱۷۸۳۸۶۸۳, Iran