COI code: TCPCO01_038
Paper Language: English
How to Download This Paper
For Downloading the Fulltext of CIVILICA papers please visit the orginal Persian Section of website.
Authors Liquid-phase oxidation of toluene with hydrogen peroxide catalyzed by Ni (ІІ), Co (ІІ), and Cu (ІІ) Schiff base complexesH. Alipournia - Department of chemistry, Faculty of science, Urmia University,Urmia,Iran
H Haghgooie - Department of chemistry, Faculty of science, Urmia University,Urmia,Iran
Abstract:There are only few reports on the selective oxidation of toluene is carried out at low temperatures using different oxidants like hydrogen peroxide, O2 etc. Peroxides are very attractive, relatively cheap and waste-avoiding oxidants.In this regard, a more environmentally benign, economically feasible and selective catalytic process is desirable. Transition metal complexes are effective and selective catalysts in a variety of organic reactions. Although these catalysts offered interesting results such as low influence of diffusion mechanisms on reaction performance, they become more useful if the separation process is tagged to recover them at the end of reaction especially for precious and strategic metal catalysts. Currently many transition metal ions complexes have been identified as homogeneous catalysts for various reactions, which showed high homogeneity, reproducibility, selectivity, and high activity to catalyze reactions under mild conditions.Schiff base complexes of transition metal ions are efficient catalysts both in homogeneous and heterogeneous reactions. The liquid phase oxidation of toluene, in the presence of several Ni (ІІ), Co (ІІ) and Cu (ІІ) Schiff base complexes using 30% aqueous hydrogen peroxide (H2O2) as oxidant, was studied. Investigations have been carried out with a view to determining the most suitable reaction conditions with respect to operating variables including reaction temperature, batch time, concentrations of the substrate, catalyst, oxidant on the overall conversion and yield of products were studied. The selective oxidation of toluene with hydrogen peroxide will produce benzaldehyde, benzoic acid, benzyl alcohol.Compared with the present synthetic method of benzaldehyde and benzyl alcohol by the chlorination of toluene followed by hydrolysis, which has been used in the world industry, the new method has the advantage of friendly environmental effects.
Keywords:Liquid phase; Toluene oxidation; Hydrogen peroxide; Schiff base complex
COI code: TCPCO01_038
how to cite to this paper:If you want to refer to this article in your research, you can easily use the following in the resources and references section:
Alipournia, H. & H Haghgooie, 2014, Liquid-phase oxidation of toluene with hydrogen peroxide catalyzed by Ni (ІІ), Co (ІІ), and Cu (ІІ) Schiff base complexes, The First National Conference of New Technologies in Chemical and Petrochemical, تهران, شركت هم انديشان چرخه علم و صنعت, https://www.civilica.com/Paper-TCPCO01-TCPCO01_038.htmlInside the text, wherever referred to or an achievement of this article is mentioned, after mentioning the article, inside the parental, the following specifications are written.
First Time: (Alipournia, H. & H Haghgooie, 2014)
Second and more: (Alipournia & Haghgooie, 2014)
For a complete overview of how to citation please review the following CIVILICA Guide (Citation)
The University/Research Center Information:
Type: state university
Paper No.: 10725
in University Ranking and Scientometrics the Iranian universities and research centers are evaluated based on scientific papers.
Research Info Management
Export Citation info of this paper to research management softwares
Iran Scientific Advertisment Netword
Share this paper
WHAT IS COI?
COI is a national code dedicated to all Iranian Conference and Journal Papers. the COI of each paper can be verified online.