Synthesis of Aniline through Palladium Nanoparticles over Alumina Catalyst
Publish place: Medbiotech Journal، Vol: 4، Issue: 2
Publish Year: 1399
نوع سند: مقاله ژورنالی
زبان: English
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شناسه ملی سند علمی:
JR_MBT-4-2_004
تاریخ نمایه سازی: 23 تیر 1399
Abstract:
Aniline was synthesized by catalytic hydrogenation of nitrobenzene (NB) on nano-sized Pd on γ-Al2O3 catalyst prepared by sol-gel method. The catalyst was characterized by SEM and XRD. The average particle of Pd catalyst was 36 nm. In hydrogenation reaction of nitrobenzene, the hydrogenation rate was zero-order with respect to nitrobenzene and increased with increasing of hydrogen pressure. Compared with commercial Pd/γ-Al2O3, catalytic activity and selectivity of the as-prepared Pd/γ-Al2O3 is superior. The reason proposed for higher catalytic activity of nano-sized Pd is the small particle size and high-density surface defects.
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Authors
Husam Ali
Department of Chemistry, Baghdad University of Technology, Baghdad, Iraq
Mahnaz Rahimisadr
Department of Chemistry, Baghdad University of Technology, Baghdad, Iraq