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Improvement of one-pot synthesis of benzothiazole by using methallophthalocyanine as catalyst under solvent-free and microwave conditions

عنوان مقاله: Improvement of one-pot synthesis of benzothiazole by using methallophthalocyanine as catalyst under solvent-free and microwave conditions
شناسه ملی مقاله: ISOC27_091
منتشر شده در بیست و هفتمین کنفرانس شیمی آلی ایران در سال 1398
مشخصات نویسندگان مقاله:

Mohsen Moradian - Department of Chemistry, Faculty of Science, Kashan of University, Kashan,۸۷۳۱۷,I.R. Iran
Sahar Mohammadi Khoshooei - Department of Chemistry, Faculty of Science, Kashan of University, Kashan,۸۷۳۱۷,I.R. Iran

خلاصه مقاله:
Benzothiazole derivatives are important heterocyclic compunds and due to their biological and pharmacological properties are used in organic and medicinal chemistry.1-2 For example,benzothiazoles are used for antitumor,3 anti-hepatitis C virus4 drugs and industrial applications as vulcanization accelerators and antioxidants. Therefore, in recent years, researchers are interested in preparation and development of benzothiazoles. There are different methods for the synthesis of benzothiazoles. This article reports the condensation reaction between 2-aminothiophenol (1) and different aldehydes (2) by using metallophthalocyanine as efficient and acsessable catalyst and under microwave irradiation (Fig.1). All synthesized compounds characterized by using spectroscopic technique such as: mass spectrum, 1H and 13C NMR and FT-IR spectroscopic data.

کلمات کلیدی:
Metallophthalocyanine, Benzothiazole, Condensation reaction, Microwave.

صفحه اختصاصی مقاله و دریافت فایل کامل: https://civilica.com/doc/1163899/