Electrocatalytic Oxidation of Ethylene Glycol on Carbon Paste Modified Electrode with Poly (n,n dimethyl aniline) /Ni-Co
عنوان مقاله: Electrocatalytic Oxidation of Ethylene Glycol on Carbon Paste Modified Electrode with Poly (n,n dimethyl aniline) /Ni-Co
شناسه ملی مقاله: PEEL04_080
منتشر شده در چهارمین همایش پیل سوختی در سال 1389
شناسه ملی مقاله: PEEL04_080
منتشر شده در چهارمین همایش پیل سوختی در سال 1389
مشخصات نویسندگان مقاله:
Banafsheh Norouzi - Department of Chemistry, Faculty of Industry and Engineering, Islamic Azad University Ghaemshahr Branch,Ghaemshahr, Iran
Mahbobeh Ahangarian - Department of Chemistry, Faculty of Industry and Engineering, Islamic Azad University Ghaemshahr Branch,Ghaemshahr, Iran
Mehdi Norouzi - ۳Faculty of Chemistry, Islamic Azad University Tehran North Branch, Tehran, Iran
خلاصه مقاله:
Banafsheh Norouzi - Department of Chemistry, Faculty of Industry and Engineering, Islamic Azad University Ghaemshahr Branch,Ghaemshahr, Iran
Mahbobeh Ahangarian - Department of Chemistry, Faculty of Industry and Engineering, Islamic Azad University Ghaemshahr Branch,Ghaemshahr, Iran
Mehdi Norouzi - ۳Faculty of Chemistry, Islamic Azad University Tehran North Branch, Tehran, Iran
The electrooxidation of ethylene glycol (EG) on CPE/Poly (N,N–dimethyl aniline)-(SDS) (CPE/PDMAN-SDS) with different proportions of Ni (II) and Co (II) in 1 M NaOH was studied by cyclic voltammetry. The results show that formed layers at the surface of the electrodes behave as an efficient electrocatalyst for the oxidation of EG in alkaline medium via the Ni (III) and Co (III) species. These modified electrodes exhibit high electrocatalytic activity and stability inalkaline solution, showing oxidation peaks at low potentials with high current densities. The effects of various parameters such as potential scan rates, EG concentration and the supporting electrolytes on the electrooxidation of EG are also investigated.
کلمات کلیدی: Electrocatalytic oxidation, Ethylene glycol, Nickel-cobalt, Alkaline medium
صفحه اختصاصی مقاله و دریافت فایل کامل: https://civilica.com/doc/116678/