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Title

Anion-Doped Overoxidized Polypyrrole/Multiwalled Carbon Nanotubes Modified Glassy Carbon Electrode as a New Electrochemical Sensing Platform For Buprenorphine Opioid Drug

Year: 1400
COI: JR_IJAC-8-1_007
Language: EnglishView: 86
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Authors

Abdolhamid Hatefi-Mehrjerdi - Department of Chemistry, Payame Noor University (PNU), P.O. Box ۱۹۳۹۵-۴۶۹۷, Tehran, Iran
Soghra Rafiei Boldaji - Department of Chemistry, Payame Noor University (PNU), P.O. Box ۱۹۳۹۵-۴۶۹۷, Tehran, Iran
Mohammad Reza Yaftian - Department of Chemistry, Faculty of Science, University of Zanjan, P.O. Box ۴۵۳۷۱-۳۸۷۹۱, Zanjan, Iran
Hassan Shayani-Jam - Department of Chemistry, Faculty of Science, University of Zanjan, P.O. Box ۴۵۳۷۱-۳۸۷۹۱, Zanjan, Iran

Abstract:

A novel Buprenorphine (BPR) sensor is fabricated based on nanocomposite film of benzene-۱,۳-disulfonate anion doped overoxidized polypyrrole/multiwalled carbon modified glassy carbon electrode. The carbon nanotubes were drop-casted on bare electrode, and then thin layer of benzene-۱,۳-disulfonate-doped overoxidized polypyrrole formed electrochemically on it. Effect of experimental conditions involving supporting electrolyte pH, carbon nanotubes suspension drop size, and the number of potential cycles in overoxidized polymerization were optimized by monitoring the voltammetry responses of the modified electrode. Then the optimized modified electrode was used for electrochemical sensing of BPR by differential pulse voltammetry, which exhibited a linear growth with high sensitivity in anodic peak currents at the BPR concentration range of ۰.۰۶-۴۰ µM, and a detection limit of ۲۸ nM. Finally, the determination of BPR in urine real samples was performed by the new sensor and satisfactory results obtained.

Keywords:

Paper COI Code

This Paper COI Code is JR_IJAC-8-1_007. Also You can use the following address to link to this article. This link is permanent and is used as an article registration confirmation in the Civilica reference:

https://civilica.com/doc/1230290/

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Hatefi-Mehrjerdi, Abdolhamid and Rafiei Boldaji, Soghra and Yaftian, Mohammad Reza and Shayani-Jam, Hassan,1400,Anion-Doped Overoxidized Polypyrrole/Multiwalled Carbon Nanotubes Modified Glassy Carbon Electrode as a New Electrochemical Sensing Platform For Buprenorphine Opioid Drug,https://civilica.com/doc/1230290

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