Efficient and Alternative Characterization of transition aluminas (η, γ, ϴ, δ-Al۲O۳) Derived from Aeroxide: Application of FT-IR and SEM

Heat treatment of Aeroxide (Alu C) at ۵۰۰ oC in high vacuumproduced reactive phase onaluminum oxide surface. While Aeroxide from Degussa shows a mixture of transition aluminas (γ, δ, and ϴ) phases, precise understanding on the development, surface morphology and microstructure of this catalytically active Al۲O۳ are not readily available. Combination of scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDS) and Fourier transform infra-red (FTIR) spectroscopy were used in this study to probe the transition alumina phase induced at the high temperature calcination. Assignment of IR bands on the pretreated sample at ۵۰۰ oC unambiguously distinguished Θ-Al۲O۳ phase which is a mixture of tetrahedral and octahedral Al۳+ sites on the face centered cubic (fcc) Oxygen sub lattice.

Keywords:

Aeroxide , Transition aluminas , Scanning electron microscopy , Energy dispersive X-ray analysis , Fourier transform infrared spectroscopy