The Use of Silica@Zn+۲ as an efficient catalyst in Diels–Alder reactions

In this study, the application of the Diels-Alder cycloaddition reactions between methyl acrylate and cyclopentadiene has been studied using a silica-supported catalyst with various concentrations of Zn۲+ ion (Silica@Zn+۲) as Lewis acid catalyst without using the solvent. The effective role of silanol groups in increasing stereoselectivities of products was also studied.

Keywords:

Diels-Alder reaction , Silica support , Cyclopentadiene , Methylacrylate , Silica@Zn+۲

Authors

G. Mohammadi Ziarani

Department of Chemistry, Faculty of physics and Chemistry, Alzahra University, Tehran, Iran

Soheila Afsharnia

Department of Chemistry, Faculty of physics and Chemistry, Alzahra University, Tehran, Iran

alireza badiei

School of Chemistry, College of Science, University of Tehran, Tehran, Iran

Negar Lashgari

Department of Chemistry, Faculty of physics and Chemistry, Alzahra University, Tehran, Iran

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لینک ثابت به این Paper:

https://civilica.com/doc/1383314

شناسه ملی سند علمی:

JR_JAOC-1-4_004

تاریخ نمایه سازی: 3 بهمن 1400

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Mohammadi Ziarani, G. and Afsharnia, Soheila and badiei, alireza and Lashgari, Negar,1400,The Use of Silica@Zn+۲ as an efficient catalyst in Diels–Alder reactions,https://civilica.com/doc/1383314

Scientometrics

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Ranking of Alzahra University

Type of center: دانشگاه دولتی

Paper count: 10,433

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