Simulation of the Structural Design of Lithium-Sulfur Batteries
Publish place: 10th International Conference on Materials Science & Metallurgical Engineering (iMat2021)
Publish Year: 1400
نوع سند: مقاله کنفرانسی
زبان: English
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شناسه ملی سند علمی:
IMES15_044
تاریخ نمایه سازی: 13 بهمن 1400
Abstract:
Lithium-sulfur (Li-S) batteries are used in niche applications with high demands for specific energy densities, which may be as high as ۵۰۰–۶۰۰ Wh/kg. A simulation is a computer program that helps in creating a real-time abstract model of a process. COMSOL, the finite element software, was used to solve the governing equations. The electrical conductivity of electrolyte and thickness of separator and cathode are among the most critical parameters of battery stability and voltage of the cell. The current study investigates the one-dimensional simulation of Li-S battery designed by graphene composite (COS) cathode, polyimide-based nano-fiber carbon anode, and optimized separator and electrolyte. This model, highly-safe lithium-sulfur batteries, is based on flame-retardant electrolyte (dimethoxyether/۱,۱,۲,۲-tetrafluoroethyl ۲,۲,۳,۳ tetrafluoropropyl ether) coupled with functional separator (MoO۳ nanobelts (MNBs) coated polypropylene (PP)) to resolve unfavorable stability of polysulfide. The results show the optimum thicknesses of cathode and separator for carbon/sulfur cathode–based lithium-sulfur batteries using this flame retardant electrolyte coupled with polypropylene (PP) coated by MoO۳ nanobelts separator are ۱۵۰, ۱۰ microns, respectively. Moreover, this could happen at the ۰.۲ charge/discharge rate and ۲.۱volts cell voltage.
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Authors
Roya Tavangar Rizi
Master Student, School of Metallurgy and Materials Engineering, College of Engineering, University of Tehran, Tehran, Iran
Elham Sarvari
Master Student, School of Metallurgy and Materials Engineering, College of Engineering, University of Tehran, Tehran, Iran
Ali Heydarinia
Master Student, School of Metallurgy and Materials Engineering, College of Engineering, University of Tehran, Tehran, Iran