Aazam Dinari - School of Chemistry, Damghan University, Damghan, Iran
Jafar Mahmoudi - School of Chemistry, Damghan University, Damghan, Iran

In this research, a modified TiO۲/Bentonite (Be) composite with various values of zinc oxide was used as a photocatalyst in the degradation of methyl orange as a dye pollutant. The synthesized composites were characterized by X-ray diffraction (XRD), Field emission scanning electron microscopy (FESEM), Fourier transform infrared spectroscopy (FTIR), X-ray fluorescence (XRF), and Thermal gravimetric analysis (TGA). The results showed that the composite synthesized by ۶.۵% zinc oxide had the highest anatase phase and appropriate thermal stability. Moreover, the simultaneous effect of different parameters was investigated using the central composite (CC) design defined under response surface methodology (RSM). The results showed that the polynomial model obtained from the analysis of variance (ANOVA) correctly predicted the experimental data. The optimal conditions of dye degradation for the synthesized composite with ۶.۵% zinc oxide using ۴ g/L of photocatalyst for ۳۰ minutes at a pH=۵ and a dye concentration of ۲۰ ppm had the highest degradation percentage equal to ۹۵% with a high desirability of ۰.۹۸۱. Also, the photocatalytic activity of TiO۲/Be/ZnO (۶.۵%) in certain conditions for reuse in five consecutive steps showed a slight decrease in the degradation of methyl orange.

TiO۲, Bentonite, zinc oxide, Methyl orange, Response surface methodology