Sol-gel synthesis of FHA / CDHA nanoparticles with a nonstochiometric ratio
Publish place: International Journal of Nano Dimension، Vol: 1، Issue: 1
Publish Year: 1389
نوع سند: مقاله ژورنالی
زبان: English
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شناسه ملی سند علمی:
JR_IJND-1-1_004
تاریخ نمایه سازی: 10 خرداد 1401
Abstract:
The aim of this study was to investigate the sol gel synthesis of HA/FA nanoparticles and the possible formation of TCP phase or unstoichiometric calcium deficient hydroxyapatite (CDHA) from the precursors with a Ca/P ratio of ۱.۶۲. In order to prepare the sol, the solutions of Triethyl phosphite, ammonium fluoride and calcium nitrate in ethanol were used respectively as P, F and Ca precursors.The crystallinity, particle and crystallite size, powder morphology, chemical structure and phase analysis were investigated by SEM, XRD, FT-IR and Zeta sizer experiment. A multiphase compound containing hydroxyapatite (HA) and fluoroapatite (FA) nanoparticles and calcium deficient hudroxyapatite (CDHA) agglomerates was obtained. The size of the crystallites estimated from XRD patterns using Scherrer equation and the crystallinity of HA phase were about ۵ nm and ۶۶% respectively. The zeta sizer experiments for the dispersed particles in its own conditions showed an average size of ۹۸ nm.
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Authors
M. Shahmohammadi
Department of Chemistry, Umea University ,Umea , Sweden.
R . Jahandideh
Biomedical Engineering Faculty, Islamic Azad University, Science and Research Branch, Tehran, Iran.
A. Behnamghader
Materials and Energy Research Center, Tehran, Iran.
M. Rangie
Department of Mechanical Engineering, Imam Hussein University, Tehran, Iran.