Supporting VO(acac)۲ and MoO۲(acac)۲ onto amine and imine-functionalized natural diatomite nanoparticles: Efficient catalysts for epoxidation of olefins using TBHP
عنوان مقاله: Supporting VO(acac)۲ and MoO۲(acac)۲ onto amine and imine-functionalized natural diatomite nanoparticles: Efficient catalysts for epoxidation of olefins using TBHP
شناسه ملی مقاله: JR_ICR-6-1_011
منتشر شده در در سال 1401
شناسه ملی مقاله: JR_ICR-6-1_011
منتشر شده در در سال 1401
مشخصات نویسندگان مقاله:
Sahar Asadi - Department of Chemistry, Shahrood University of Technology, Shahrood, Iran
Bahram Bahramian - Department of Chemistry, Shahrood University of Technology, Shahrood, Iran
Vahid Mirdarvatan - Department of Chemistry, Shahrood University of Technology, Shahrood, Iran
خلاصه مقاله:
Sahar Asadi - Department of Chemistry, Shahrood University of Technology, Shahrood, Iran
Bahram Bahramian - Department of Chemistry, Shahrood University of Technology, Shahrood, Iran
Vahid Mirdarvatan - Department of Chemistry, Shahrood University of Technology, Shahrood, Iran
AbstractThe natural diatomite nanoparticles (Dt) were covalently functionalized by ۳-(trimethoxysilyl)-propylamine (MSPA) and salicylaldehyde to support VO(acac)۲ and MoO۲(acac)۲ precursor complexes. The prepared compounds were characterized by FT-IR, PXRD, SEM, EDX, ICP, and BET techniques. Then they were used to catalyze the heterogeneous epoxidation of cis‐cyclooctene as a model alkene using tert-butyl hydroperoxide (TBHP). Various parameters that affect catalytic efficiency were investigated, and the optimized experimental conditions were successfully used for the epoxidation of other linear and non-linear alkenes. The important advantages of these new catalytic systems are their simple preparation, low catalyst loading, and high product yield. Moreover, these catalysts can be used up to three times for an efficient epoxidation of cis‐cyclooctene.
کلمات کلیدی: Diatomite nanoparticles, Alkene epoxidation, Vanadium, Molybdenum
صفحه اختصاصی مقاله و دریافت فایل کامل: https://civilica.com/doc/1535021/