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Synthesis and Characterization of a Novel Crowned Schiff Base Ligand Linked to Ionic Liquid and Application of Its Mn(III) Complex in the Epoxidation of Olefins

عنوان مقاله: Synthesis and Characterization of a Novel Crowned Schiff Base Ligand Linked to Ionic Liquid and Application of Its Mn(III) Complex in the Epoxidation of Olefins
شناسه ملی مقاله: JR_CHM-7-5_006
منتشر شده در در سال 1402
مشخصات نویسندگان مقاله:

Sanaz Naderi - Department of Chemistry, Faculty of Science, University of Birjand, Birjand, Iran
Reza Sandaroos - Department of Chemistry, Faculty of Science, University of Birjand, Birjand, Iran
Sahar Peiman - Department of Organic Chemistry, Faculty of Chemistry, University of Mazandaran, Babolsar, Iran
Behrooz Maleki - Department of Organic Chemistry, Faculty of Chemistry, University of Mazandaran, Babolsar, Iran

خلاصه مقاله:
A new Schiff base ligand bound to ionic liquid and crown ether was synthesized and complexed with Mn (III) metal. Manganese complex was used in the vicinity of oxone oxidant and the absence of an axial base in water-chloroform biphasic oxidation to oxidize different alkenes, the corresponding epoxides were obtained with ۷۰-۹۶% yields. The lowest efficiency is related to alkenes with electron-withdrawing groups.

کلمات کلیدی:
Schiff base, Ionic Liquid, Crown Ether, Oxone, Epoxidation

صفحه اختصاصی مقاله و دریافت فایل کامل: https://civilica.com/doc/1620275/