Sobhan Rezayati - Department of Chemistry, Faculty of Science, University of Zanjan, Zanjan ۴۵۳۷۱-۳۸۷۹۱, Iran
Zahra Naserifar - Department of Chemistry, Faculty of Science, University of Zanjan, Zanjan ۴۵۳۷۱-۳۸۷۹۱, Iran
Ali Ramazani - Department of Chemistry, Faculty of Science, University of Zanjan, Zanjan ۴۵۳۷۱-۳۸۷۹۱, Iran,Department of Biotechnology, Research Institute of Modern Biological Techniques (RIMBT), University ofZanjan, Zanjan ۴۵۳۷۱-۳۸۷۹۱, Iran

An eco-friendly, highly efficient, and novel sulfonic acid functionalized imidazolium thiocyanate (Imidazole-SO۳H)/SCN and sulfonic acid functionalized imidazolium chloride (Imidazole-SO۳H)/Cl solid acid catalyst were successfully synthesized. The structure of catalyst was characterized by various analyses such as FT-IR, ۱H NMR and ۱۳C NMR spectroscopy. The thiocyanation reaction of various electron rich arenes such as anilines, indoles, phenols, and other aromatic compounds were selected to show the catalytic performance and efficiency of the as-prepared solid acid catalyst, and excellent yields of the corresponding aryl and heteroaryl thiocyanates derivatives were obtained under metal-free and green conditions in water. In addition, one of the important features of current method is when the thiocyanation reaction is carried out with (Imidazole-SO۳H)/SCN, this reagent has a dual role in the reaction, both as thiocyanation agent and as acidic group. On the other hand, (Imidazole-SO۳H)/Cl as a catalyst plays just as acidic group in reaction.

(Imidazole-SO۳H)/SCN; (Imidazole-SO۳H)/Cl; thiocyanation; regioselectivity; eco-friendly chemistry; metal-free