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A Novel Equation of State Correlation for Solute Solubility in Supercritical Fluids

عنوان مقاله: A Novel Equation of State Correlation for Solute Solubility in Supercritical Fluids
شناسه ملی مقاله: NICEC14_103
منتشر شده در چهاردهمین کنگره ملی مهندسی شیمی ایران در سال 1391
مشخصات نویسندگان مقاله:

Milad Asgarpour Khansary - School of Chemical Engineering, University College of Engineering, University of Tehran, Tehran, Iran
Ahmad Hallaji Sani - School of Chemical Engineering, University College of Engineering, University of Tehran, Tehran, Iran
Farshad Amiri
Ashkan Hosseini

خلاصه مقاله:
Based on Pitzer correlations for the compressibility factor and virial equation of state, a new equation of state has been developed by authors, which is a function of total number of atomspresent in the solute molecule, normal boiling point temperature and reduced temperature. Peng- Robinson EOS, together with two adjustable parameter Van der Waals mixing rules, and the proposed EOS are used for correlation of 60 drugs solubility in this paper. As the results show, theproposed EOS presents more accurate predictions for solubility data in Supercritical CarbonDioxide. So it can be employed to accelerate the industrial processes

کلمات کلیدی:
equation of state, compressibility factor, supercritical fluid, solubility, drugs

صفحه اختصاصی مقاله و دریافت فایل کامل: https://civilica.com/doc/171721/