MECHANO-THERMAL REDUCTION OF HEMATITE AND ANATASE MIXTURE BY TWO DIFFERENT FORMS OF CARBON AS REDUCTANT FOR IN-SITU PRODUCTION OF Fe-T iC - NANO CRYSTALLINE COMPOSITE
عنوان مقاله: MECHANO-THERMAL REDUCTION OF HEMATITE AND ANATASE MIXTURE BY TWO DIFFERENT FORMS OF CARBON AS REDUCTANT FOR IN-SITU PRODUCTION OF Fe-T iC - NANO CRYSTALLINE COMPOSITE
شناسه ملی مقاله: JR_IJMSEI-12-2_007
منتشر شده در در سال 1394
شناسه ملی مقاله: JR_IJMSEI-12-2_007
منتشر شده در در سال 1394
مشخصات نویسندگان مقاله:
S. Niksirat - School of Metallurgy and Materials Engineering, College of Engineering, University of Tehran, Tehran, Iran.
SH. Raygan - School of Metallurgy and Materials Engineering, College of Engineering, University of Tehran, Tehran, Iran.
S. Moradi Ghiassabadi - School of Metallurgy and Materials Engineering, College of Engineering, University of Tehran, Tehran, Iran.
خلاصه مقاله:
S. Niksirat - School of Metallurgy and Materials Engineering, College of Engineering, University of Tehran, Tehran, Iran.
SH. Raygan - School of Metallurgy and Materials Engineering, College of Engineering, University of Tehran, Tehran, Iran.
S. Moradi Ghiassabadi - School of Metallurgy and Materials Engineering, College of Engineering, University of Tehran, Tehran, Iran.
In this research, two different carbonaceous materials (Graphite:G and Petrocoke:P) were separately
compared in terms of the carbothermic reduction of hematite and anatase in order to synthesize Fe-TiC nanocrystalline composite by mechanically activated sintering method. Powders were activated in a planetary high-energy
ball mill under argon atmosphere for ۰, ۲, ۵, ۱۰,and ۲۰ h. Then, the activated powders were analyzed by XRD and
SEM to investigate phase constituents and microstructure of the mixtures. Results proved that Fe
۲
O
۳
and TiO
۲
were not
reduced by carbonaceous materials even after ۲۰h of milling. SEM investigations showed that G-mixture was more
homogenous than P-mixture after ۲۰h of milling, meaning that graphite-anatase-hematite was mixed satisfactorily.
Thermogravimetry analysis was done on ۰ and ۲۰h milled powders. TG and DTG curves showed that mechanical
activation led to almost ۳۰۰°C decrease in the reduction temperature of hematite and anatase in both mixtures. In the
next step, the powders were sintered in a tube furnace under argon atmosphere. In the G-mixture, anatase was reduced
to titanium carbide at ۱۱۰۰°C but, in the P-mixture, temperature of ۱۲۰۰°C was essential for completely reducing
anatase to titanium carbide.Results of phase identification of the sintered powders showed that anano-crystalline ironbased composite with titanium carbide, as the reinforcement was successfully synthesized after ۲۰ h high-energy
milling of the initial powders and subsequent sintering occurred at ۱۲۰۰˚C for ۱h
کلمات کلیدی: Mechanical Activation, Heat Treatment, Fe-TiC, Nano-crystalline Composite, Petrocoke, Graphite.
صفحه اختصاصی مقاله و دریافت فایل کامل: https://civilica.com/doc/1723166/