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An Efficient Synthesis of Vinylphosphonates from AlkylCyanoformates, Activated Acetylenes, and Trialkyl Phosphites

عنوان مقاله: An Efficient Synthesis of Vinylphosphonates from AlkylCyanoformates, Activated Acetylenes, and Trialkyl Phosphites
شناسه ملی مقاله: COSPC01_046
منتشر شده در کنفرانس ملی سنتز آلی و شیمی دارویی در سال 1392
مشخصات نویسندگان مقاله:

Tayebeh Sanaeishoar - Young Researchers Club, Khouzestan Science and Research Branch, Islamic Azad University,Ahvaz, Iran
Tahereh Shojaee - Department of chemistry, College of Science, Khouzestan Science and Research Branch,Islamic Azad University, Ahvaz, Iran
Parvaneh Shabankareh - Department of chemistry, College of Science, Khouzestan Science and Research Branch,Islamic Azad University, Ahvaz, Iran
Mina Bashirpour - Department of chemistry, College of Science, Khouzestan Science and Research Branch,Islamic Azad University, Ahvaz, Iran

خلاصه مقاله:
An efficient synthesis of vinylphosphonates is described. This involves the reaction ofalkyl cyanoformates and dialkyl acetylendicarboxylates in the presence of trialkyl phosphites.The ۱H, ۱۳C NMR, and ۳۱P NMR spectra of vinylphosphonates having different substitution areconsistent with the presence of two geometrical isomers

کلمات کلیدی:
Vinylphosphonates, Alkyl cyanoformates, Acetylenic esters, Trialkyl phosphites

صفحه اختصاصی مقاله و دریافت فایل کامل: https://civilica.com/doc/1764600/