Efficient Oxidative Dehydrogenation of Dihydropyrimidinones and Thiocyanation of Aromatic Compounds Using ۱,۱,۲,۲-Tetrahydroperoxy-۱,۲-diphenylethane as the Oxidant
عنوان مقاله: Efficient Oxidative Dehydrogenation of Dihydropyrimidinones and Thiocyanation of Aromatic Compounds Using ۱,۱,۲,۲-Tetrahydroperoxy-۱,۲-diphenylethane as the Oxidant
شناسه ملی مقاله: JR_ORGC-5-2_003
منتشر شده در در سال 1398
شناسه ملی مقاله: JR_ORGC-5-2_003
منتشر شده در در سال 1398
مشخصات نویسندگان مقاله:
Kaveh Khosravi - Faculty of Science, Department of Chemistry, Arak University, Arak ۳۸۱۵۶-۸-۸۳۴۹, Iran.
Amir Azizi - Faculty of Science, Department of Chemistry, Arak University, Arak ۳۸۱۵۶-۸-۸۳۴۹, Iran
Shirin Naserifar - Faculty of Science, Department of Chemistry, Arak University, Arak ۳۸۱۵۶-۸-۸۳۴۹, Iran.
خلاصه مقاله:
Kaveh Khosravi - Faculty of Science, Department of Chemistry, Arak University, Arak ۳۸۱۵۶-۸-۸۳۴۹, Iran.
Amir Azizi - Faculty of Science, Department of Chemistry, Arak University, Arak ۳۸۱۵۶-۸-۸۳۴۹, Iran
Shirin Naserifar - Faculty of Science, Department of Chemistry, Arak University, Arak ۳۸۱۵۶-۸-۸۳۴۹, Iran.
A new, efficient and mild approach for the oxidative dehydrogenation of dihydropyrimidinones and thiocyanation of aromatic compounds using ۱,۱,۲,۲-tetrahydroperoxy-۱,۲-diphenylethane (THPDPE) as a terminal oxidant was developed. Initially, various substrates bearing different electron-donating and electron-releasing functionalities were synthesized and next under the optimized reaction conditions the desired products were yielded after an easy work-up and the structures were characterized compared with those reported. All of the reactions proceeded in short reaction times and ۱,۱,۲,۲-tetrahydroperoxy-۱,۲-diphenylethane (THPDPE) proved its potential to yield the desired products in high yields.
کلمات کلیدی: Dehydropirimidinones, Oxidative dehydrogenation, Thiocyanation, ۱, ۲, ۲-Tetrahydroperoxy-۱, ۲-diphenylethane, Pyrimidinones
صفحه اختصاصی مقاله و دریافت فایل کامل: https://civilica.com/doc/1766175/