Manzar Akbari - Department of Chemistry, Faculty of Science, Ilam University, P. O. Box ۶۹۳۱۵۵۱۶, Ilam, Iran
Mohsen Nikoorazm - Department of Chemistry, Faculty of Science, Ilam University, P. O. Box ۶۹۳۱۵۵۱۶, Ilam, Iran
Bahman Tahmasbi - Department of Chemistry, Faculty of Science, Ilam University, P. O. Box ۶۹۳۱۵۵۱۶, Ilam, Iran
Arash Ghorbani-Choghamarani - Department of Organic Chemistry, Faculty of Chemistry, Bu-Ali Sina University, Hamedan, Iran

Many Pd complexes have been used as homogeneous catalysts in cross-coupling reactions [۱].Although some of the Pd complexes have potential for recycling [۲,۳], most of them have problemssuch as deactivation and difficult separation from the solution. Thus, it is necessary to developheterogeneous catalysts which can easily be recovered from the reaction system and reused [۴, ۵].Recently, Ryoo and co-workers reported a new cubic mesoporous silica material named KIT-۶,which was prepared using triblock copolymer (P۱۲۳) as the mesopore directing agent. KIT-۶possesses large readily tunable pores with thick pore walls, high thermal stability, high specificsurface area and large pore volume. Therefore, mesoporous KIT-۶ can be used as a support for thesynthesis heterogeneous catalysts. In this work, a new Schiff base complex of Pd(II) was fabricatedon the surface of KIT-۶. For this purpose Schiff-base ligand was synthesized from condensationof diethylenetriamine (DETA) and salicylic aldehyde (SA). In the next step, Schiff-base ligandwas reacted with (۳-iodopropyl)trimethoxy silane (IPTMS). Then, Schiff base complex ofpalladium was synthesized using a complexation reaction of Pd(OAc)۲. Finally, the obtainedpalladium complex was fixed on KIT-۶ (Pd@SA-Schiff base@KIT-۶) as a new reusable andpractical catalyst in Suzuki reaction. This catalyst was characterized using IR, BET, EDS, SEM,and TGA methods.

Mesoporous silica materials, Nanocatalyst, Suzuki reaction, KIT-۶, Schiff base complex,Palladium.