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Aluminium -based ionic liquid grafted on Biochar as a heterogeneouscatalyst for the synthesis of ۲,۳-dihydroquinazolin-۴(۱H)-one

عنوان مقاله: Aluminium -based ionic liquid grafted on Biochar as a heterogeneouscatalyst for the synthesis of ۲,۳-dihydroquinazolin-۴(۱H)-one
شناسه ملی مقاله: IICC22_176
منتشر شده در بیست و دومین کنفرانس شیمی معدنی ایران در سال 1402
مشخصات نویسندگان مقاله:

Masoomeh Norouzi - Department of Chemistry, Faculty of Science, Ilam University, P.O. Box ۶۹۳۱۵۵۱۶, Ilam, Iran.

خلاصه مقاله:
Biomass as the only carbon neutral alternative, has the unique chemical structure containingtailored surface functional groups and large surface area. Having these features has made it easyto prepare by activation and/or functionalization.The selection of biochar as a surface will be idealfor the preparation of heterogeneous catalysis [۱, ۲]. Recently, ionic liquids are suitable substitutefor old conventional catalyst and do not leave any toxicity in the reaction medium [۳]. Aluminium-based ionic liquid grafted on biochar surface (BC\[TESPMI]۲AlCl۳) was synthesized as a catalystfor the synthesis of ۲,۳-dihydroquinazolin-۴(۱H)-one and characterized by FTIR, XRD, TGA,FESEM, and EDS. This results disclosed that the chemical grafting was successfully performed.The high activity in mild condition and the simple recoverable from the reaction are the suitablecharacteristics of this catalyst. Finally, the catalyst sustained activity for five cycles of reaction

کلمات کلیدی:
Biochar, ۲,۳-dihydroquinazolin-۴(۱H)-one, Ionic liquid, Recoverable nanocatalyst

صفحه اختصاصی مقاله و دریافت فایل کامل: https://civilica.com/doc/1832350/