Nastaran Hazrati - Department of Chemistry, Amirkabir University of Technology, Tehran, Iran
Ali Akbar Miran Beigi - Oil Refining Research Division, Research Institute of Petroleum Industry, Tehran, Iran
Majid Abdouss - Department of Chemistry, Amirkabir University of Technology, Tehran, Iran
Amir Vahid - Oil Refining Research Division, Research Institute of Petroleum Industry, Tehran, Iran

The nano-sized structure of well-ordered Zn@MCM-۴۱ adsorbent was synthesized through a direct hydrothermal method using CTAB as a structure-directing agent in an ammonia aqueous solution with different amounts of zinc acetylacetonate which were inserted into the structure-directing agent’s loop during the synthesis. The XRD, HRTEM, and N۲ adsorption-desorption isotherms were used to characterize the prepared ZnO functionalized mesoporous silica samples. As a result, the presence of ZnO in highly-ordered MCM- ۴۱’s pore was proved as well as maintenance of the ordered mesostructure of MCM-۴۱. The materials were possessed with a high specific surface area (۱۱۱۴-۵۰۹ m۲ g-۱) and a large pore diameter (۴.۰۳-۳.۲۷ nm). Based on the obtained results from the adsorption of H۲S gas in a lab-made setup, the Znx@MCM-۴۱ showed the superior ability to increase of ZnO amount up to ۷ hours as a breakthrough point. A two factor (zinc percent and temperature) experimental design with three levels was accomplished to optimize the adsorption parameters. The influence of parameters and the interactions on the adsorption of H۲S were studied and optimized. Also, the H۲S breakpoint curves carried on by UOP۱۶۳ method.

Zinc encapsulated MCM-۴۱, H۲S gas, Adsorption, Extraction, UOP۱۶۳ method