Separation of aniline from water and wastewater samples based on activated carbon nanoparticles and dispersive solid phase extraction procedure

The water, wastewater and air are the main sources of aniline in environment. Aniline has a toxic effect in the human body and environment and so, must be determined by novel techniques. In this study, the activated carbon with microwave heating methods (MHM-ACNPs) were used for extraction aniline from waters by dispersive ionic liquid solid phase extraction procedure (D-IL-SPE) and compared to the activated carbon (AC). For this purpose, the mixture of acetone, ionic liquid and ۳۰ mg of MHM-ACNPs/ AC added to ۱۰۰ mL of water samples at pH=۸. After sonication for ۱۰ min, the benzene ring in aniline as electron acceptor was chemically adsorbed on carboxylic groups of MHM-ACNPs as electron donors (MHM-ACNPs-COO─……C۶H۵-NH۲) and then, the adsorbent was collected by hydrophobic ionic liquid phase in bottom of conical centrifuging tube. Finally, the aniline was released from MHM-ACNPs in remained solution by changing pH and the concentration of aniline determined by gas chromatography–flame ionization detector (GC-FID). The working range (WR) was obtained from ۲.۰ to ۴۰۰۰ μg L-۱ (RSD % < ۱.۸). The detection limit (LOD) and preconcentration factor (PF) and linear range (LR) were achieve ۰.۶ μg L-۱, ۱۹۶.۴ and ۲.۰─۹۵۰ μg L-۱, respectively. The proposed method was validated by spiking of real samples and analysis with gas chromatography mass detector (GC-MS).

Keywords:

Aniline , Activated carbon nanoparticles , Ionic liquid , Dispersive solid phase extraction procedure , gas chromatography–mass spectrometry