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N۲-bubbling Method for O۲ Removal from the Loaded MEA Solution in the CO۲ Capture Process

عنوان مقاله: N۲-bubbling Method for O۲ Removal from the Loaded MEA Solution in the CO۲ Capture Process
شناسه ملی مقاله: JR_JPSTR-13-1_004
منتشر شده در در سال 1402
مشخصات نویسندگان مقاله:

Mohammad Shokouhi - Gas Refining Technology Group, Gas Research Division, Research Institute of Petroleum Industry (RIPI), Tehran, Iran.
Ali Zoghi - Gas Refining Technology Group, Gas Research Division, Research Institute of Petroleum Industry (RIPI), Tehran, Iran.\Natural Gas Sweetening Group, Gas Processing Institute (GPI), Tehran, Iran.
Mehrnoosh Mehrabi - Gas Refining Technology Group, Gas Research Division, Research Institute of Petroleum Industry (RIPI), Tehran, Iran.
maryam abbasghorbani - Gas Refining Technology Group, Gas Research Division, Research Institute of Petroleum Industry (RIPI), Tehran, Iran.
Akbar Zamaniyan - Downstream Research Center, Research Institute of Petroleum Industry (RIPI),Tehran, Iran
Ehsan Zhaleh Rajabi - Department of Chemical Engineering, Universiti of Teknologi Petronas, malysia

خلاصه مقاله:
Flue gas stream contains full-oxidized (carbon dioxide), partially oxidized hydrocarbons, and some extent of oxygen. Carbon dioxide can be separated by CO۲ capture and separation (CCS) process using monoethanolamine (MEA). In this process, CO۲ accompanied with O۲ can be absorbed by the solution (MEA+H۲O). Dissolved molecular oxygen may explicitly participate in the cathodic reaction and generate sever corrosion problems, or it may induce amine degradation via irreversible oxidative reaction, reducing amine efficiency. In this research, the method of N۲-bubbling was investigated for deoxygenation of loaded aqueous MEA solution on a laboratory scale. N۲-bubbling set-up was simulated with a known volume glass vessel in which bubbling of N۲ with an available flow rate was applied through the loaded amine solution. A mathematical formula was developed to correlate the N۲-bubbling flow rate, F, the volume of amine solution in the bubbling column, V, and time taking the oxygen concentration decreases from saturated O۲-solution to less than ۰.۵ mg/L.

کلمات کلیدی:
CO۲ capture, De-oxygenation, Dissolved oxygen, monoethanolamine solution, N۲-Bubbling

صفحه اختصاصی مقاله و دریافت فایل کامل: https://civilica.com/doc/1859680/