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Bis[(۲-ethoxy-۲-oxoethyl)triphenyl phosphonium] di-µ-chloro-bis[bromochloro palladate (II)] and its application in Heck and Suzuki cross-coupling reactions

عنوان مقاله: Bis[(۲-ethoxy-۲-oxoethyl)triphenyl phosphonium] di-µ-chloro-bis[bromochloro palladate (II)] and its application in Heck and Suzuki cross-coupling reactions
شناسه ملی مقاله: JR_CHRL-7-2_006
منتشر شده در در سال 1403
مشخصات نویسندگان مقاله:

Ali Naghipour - Department of Chemistry, Faculty of science, Ilam University, Ilam, Ilam ۶۹۳۱۵-۵۱۶, Iran.
Abozar Bastami - Department of Chemistry, Faculty of Science, Ilam University, Ilam, Iran.
Ali khatibjoo - Department of Animal Science, Faculty of Agriculture, Ilam University, Ilam- Iran
Fatahnia Farshid - Department of Animal Science, Faculty of Agriculture, Ilam University, Ilam- Iran.

خلاصه مقاله:
In this study, the phosphonium salt [Ph۳PCHC(O)OCH۲CH۳]Br undergoes a reaction with palladium(II) chloride, resulting in the formation of [Ph۳PCHC(O)OCH۲CH۳]۲[Pd۲Cl۴Br۲]. The synthesized compound underwent thorough characterization through elemental analysis, as well as FT-IR, ۱H, ۳۱P, and ۱۳C NMR spectroscopies. The investigation revealed that this particular substance serves as an efficient catalyst for the Heck cross-coupling reaction, leading to the synthesis of diverse unsaturated products with highly favorable outcomes. Moreover, it has demonstrated effectiveness in catalyzing the Suzuki cross-coupling reaction. Notably, the catalyst exhibits sustained catalytic activity and can be conveniently recovered and reused.

کلمات کلیدی:
Phosphonium salt, Palladium(II), Heck C-C coupling, Suzuki cross-coupling

صفحه اختصاصی مقاله و دریافت فایل کامل: https://civilica.com/doc/1943718/