ZnSO4.7H2O Supported Thiourea: an Efficient Reagent for Synthesis of Thiiranes from Epoxides
Publish Year: 1392
نوع سند: مقاله کنفرانسی
زبان: English
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شناسه ملی سند علمی:
CAAT03_153
تاریخ نمایه سازی: 29 بهمن 1392
Abstract:
Thiirane is found in naturally occurring compounds, herbicides, pesticides, polymeric compounds,pharmaceuticals, and in many other manmade chemicals [1]. Transformation of epoxides to thiiranes by anoxygen–sulfur exchange reaction is a useful reaction and has been achieved with various methods usingsulfur transfer agents [2-3]. ZnSO4.7H2O is inexpensive, efficient, readily available, and mild catalyst, whichhas surface properties, and suggests very rich organic chemistry. Zinc sulfate is the inorganic_compoundwith the formula ZnSO4 as well as any of three hydrates . It was historically known as white vitriol . It is acolorless solid that is a common source of soluble zinc ions [4].Herein, we wish to introduce a simple and efficient method for conversion of oxiranes to theircorresponding thiiranes using thiourea supported on ZnSO4.7H2O under nonaqueous conditions in refluxingacetonitrile. The capability of this synthetic protocol was investigated by the reaction of activated,deactivated, and cyclic epoxides with thiourea/ ZnSO4.7H2O system under the optimized conditions. Theepoxides were converted to the corresponding thiiranes in exellent yields within short times (Scheme 1).
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Authors
Rasool Daryaie
Department of Chemical Engineering , Faculty of Engineering,Islamic Azad University, Ahar,Iran;
Ronak Eisavi
Department of Chemistry, Payame Noor Universtiy, PO BOX ۱۹۳۹۵-۳۶۹۷ Tehran, Iran;
Kamel Ahmadi Lavin
Department of Chemical Engineering , Faculty of Engineering,Islamic Azad University, Ahar,Iran
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