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Nanocatalyst based on heteropolyacid supported on clay as catalyst for the synthesis of 3,4-dihydropyrimidin-2(1H)-ones/thiones under solvent-free conditions

عنوان مقاله: Nanocatalyst based on heteropolyacid supported on clay as catalyst for the synthesis of 3,4-dihydropyrimidin-2(1H)-ones/thiones under solvent-free conditions
شناسه ملی مقاله: TCPCO01_329
منتشر شده در اولین همایش ملی تکنولوژی های نوین در شیمی و پتروشیمی در سال 1393
مشخصات نویسندگان مقاله:

Elham Dezfooli Nezhad - Department of Chemistry, Islamic Azad University, ahvaz, Iran
Ali Ezabadi - Department of Chemistry, Islamic Azad University,Central Branch, Tehran, Iran

خلاصه مقاله:
A simple and efficient synthesis of 3,4-dihydropyrimidin-2(1H)-ones or 3,4-dihydropyrimidin-2(1H)-thiones is described, using 20% w/w Cs2.5H0.5PW12O40/K-10 as a solid acidcatalyst from an aldehyde, 1,3-dicarbonyl compound, and urea or thiourea at 80 °C under solvent-freeconditions. Short reaction times, high yields, easy work-up, use of environmentally friendly catalyst and absence of organic solvents makes this method efficient and environmentally benign

کلمات کلیدی:
Biginelli reaction, solid acid catalyst, 3,4-dihydropyrimidin-2(1H)-ones, solvent-free condition,heteropolyaci d

صفحه اختصاصی مقاله و دریافت فایل کامل: https://civilica.com/doc/244551/