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Densities, viscosities, excess molar volumes of ternary systems n-propyl acetate + 2-butanol + 2-pentanol at T=298.15 K.

عنوان مقاله: Densities, viscosities, excess molar volumes of ternary systems n-propyl acetate + 2-butanol + 2-pentanol at T=298.15 K.
شناسه ملی مقاله: NCTCC03_122
منتشر شده در سومین همایش ملی فن آوری های نوین شیمی و مهندسی شیمی در سال 1393
مشخصات نویسندگان مقاله:

Fatemeh Ebrahimi - Faculty of Chemistry, Bu-Ali Sina University, Hamedan ۶۵۱۷۸, Iran
Jalal Basiri Parsa - Faculty of Chemistry, Bu-Ali Sina University, Hamedan ۶۵۱۷۸, Iran

خلاصه مقاله:
Density, viscosity and refractive indices ( n(D) ) of ternary mixtures of n-propylacetate + 2-butanol + 2-pentanol and their binary systems n-propylacetate + 2-butanol, 2-butanol +2-pentanol and n-propylacetate + 2-pentanol have been studied at 298.15 K and atmosphericpressure. From the experimental data, the excess molar volumes ( V(E) ), viscosity deviation (Δ ƞ ),absolute synergies of refractive index deviation (Δ n(D) and excess Gibbs free energy ofactivation (Δ G(*E) ) have been calculated. These results have been correlated as a function of molefraction with the Redlich-Kister equation for the binary mixtures and with the Cibulka equationfor the ternary mixture.

کلمات کلیدی:
Excess properties; Ternary; Propylacetate; 2-Butanol; 2-Pentanol

صفحه اختصاصی مقاله و دریافت فایل کامل: https://civilica.com/doc/283444/