CO2 Reforming of Methane over Nickel Catalysts Supported on Nanocrystalline MgAl2O4 with High Surface Area
Publish place: 07th International Congress on Chemical Engineering
Publish Year: 1390
نوع سند: مقاله کنفرانسی
زبان: English
View: 660
This Paper With 9 Page And PDF Format Ready To Download
- Certificate
- من نویسنده این مقاله هستم
استخراج به نرم افزارهای پژوهشی:
شناسه ملی سند علمی:
ICHEC07_336
تاریخ نمایه سازی: 25 فروردین 1394
Abstract:
In this paper Dry reforming of methane (DRM) was carried out over MgAl2O4 supported Ni catalysts with various Ni loadings. MgAl2O4 spinel with high specific surface area, as nanocrystalline carrier for nickel catalysts, was synthesized by co-precipitation method with the addition of pluronic P123 triblock copolymer as surfactant. The prepared samples were characterized by XRD, N2 adsorption (BET), H2 chemisorption,Temperature programmed desorption (TPD) and Scanning electron microscopy (SEM) techniques. The obtained results showed that the catalyst support has a high specific surface area and a nanocrystalline structure. In addition, the specific surface area of calcined catalysts decreased with increasing Ni loading. The catalytic activity measurment results showed a high activity and stability of prepared catalysts during time on stream which could be attributable to high dispersion of reduced Ni species. In addition, the effect of feed ratio, Ni loading and GHSV on the catalytic performance of DRM over the catalysts were investigated.
Keywords:
Authors
n Hadian
Institute of Nanoscience and Nanotechnology, University of Kashan, Kashan, Iran
m Rezaei
Institute of Nanoscience and Nanotechnology, University of Kashan, Kashan, Iran Catalyst and Advanced Materials Research Laboratory, Chemical Engineering Department, Faculty of Engineering, University of Kashan, Kashan, Iran
z Mosayebi
Institute of Nanoscience and Nanotechnology, University of Kashan, Kashan, Iran
f Meshkani
Catalyst and Advanced Materials Research Laboratory, Chemical Engineering Department, Faculty of Engineering, University of Kashan, Kashan, Iran
مراجع و منابع این Paper:
لیست زیر مراجع و منابع استفاده شده در این Paper را نمایش می دهد. این مراجع به صورت کاملا ماشینی و بر اساس هوش مصنوعی استخراج شده اند و لذا ممکن است دارای اشکالاتی باشند که به مرور زمان دقت استخراج این محتوا افزایش می یابد. مراجعی که مقالات مربوط به آنها در سیویلیکا نمایه شده و پیدا شده اند، به خود Paper لینک شده اند :