Applying full factorial design to the optimization of H-ZSM-5 zeolite synthesis for methanol dehydration to dimethyl ether

H-ZSM-5 zeolite was synthesized by hydrothermal method. The effects of different synthesis parameters, including temperature (170−190 °C) and Si/Al molar ratio (100−150) on the catalyst performance in the dehydration of methanol to dimethyl ether (DME) were studied. The catalystswere characterized by BET, XRD, NH3-TPD, TGA/DTA, and SEM techniques. The full factorialdesign of experiments was applied to synthesis of ZSM-5 zeolite and the effects of synthesisconditions and their interaction on the yield of DME as the response variable were determined. Analysis of variance showed that two variables and their interaction significantly affected the response. According to the experimental results, the optimized catalyst prepared at 170 ºC andSi/Al = 100 molar ratio showed better performance compared with those prepared at other conditions.

Keywords:

Full factorial design , ZSM-5 synthesis , Hydrothermal method , Dimethyl ether