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Modification of clay via silane grafting and nylon synthesis onto the montmorillonite

عنوان مقاله: Modification of clay via silane grafting and nylon synthesis onto the montmorillonite
شناسه ملی مقاله: ICHEC07_508
منتشر شده در هفتمین کنگره ملی مهندسی شیمی در سال 1390
مشخصات نویسندگان مقاله:

ali yadegari - Polymer Science Department, Faculty of Science, Iran Polymer and Petrochemical Institute, Tehran, Iran
hamid salehi mobarakeh - Polymer Science Department, Faculty of Science, Iran Polymer and Petrochemical Institute, Tehran, Iran
fahimeh Khakzad-Esfahlan - Polymer Science Department, Faculty of Science, Iran Polymer and Petrochemical Institute, Tehran, Iran
Alireza Mahdavian - Polymer Science Department, Faculty of Science, Iran Polymer and Petrochemical Institute, Tehran, Iran

خلاصه مقاله:
Chemical modification of montmorillonite clay has been carried out using a trifunctional alkoxysilane (3-aminopropyl)triethoxysilane (γ-APS). Silane grafting was achieved in dry andhydrolyzing conditions. Pristine and silane grafted clay took part in interfacial polycondensation (IPC) process to synthesis a layer of polyamide-66 onto the clay lamellae and therefore, enhance their affinity with polyamide-66 matrix. Evidence of presence of grafted silane molecules andpresence of polyamide-66 on clay particles were provided by Fourier transform infrared (FTIR), thermogravimetric analysis (TGA) and X-ray diffraction (XRD). Affinity evaluation of such modified clays with polyamide-66 matrix was inspected through melt compounding of them with polyamide-66 in another work

کلمات کلیدی:
Montmorillonite, Organosilane, Interfacial Polycondensation

صفحه اختصاصی مقاله و دریافت فایل کامل: https://civilica.com/doc/341258/