Effect of pH on the synthesis of ZSM-5 zeolite using TEOS and performance of H-ZSM-5 catalyst in propane aromatization
Publish place: 15th Iranian Natioanl Congress of Chimical Engineering
Publish Year: 1393
نوع سند: مقاله کنفرانسی
زبان: English
View: 1,037
This Paper With 5 Page And PDF Format Ready To Download
- Certificate
- من نویسنده این مقاله هستم
استخراج به نرم افزارهای پژوهشی:
شناسه ملی سند علمی:
ICHEC15_335
تاریخ نمایه سازی: 19 تیر 1394
Abstract:
Effect of alkalinity on the hydrothermal synthesis of ZSM-5 zeolite using TEOS as the Si source, TPABr as the template and NaAlO2 as the Al source was studied. Formation of the crystal phases was investigated throughout X-Ray Diffraction. BET, SEM and NH3-TPD techniques were also applied for product characterization. The results indicated the significant effect of the hydrogel alkalinity on the product specifications. Actually, different levels of alkalinity can hinder formation of crystalline phase or result in growth of other phases which are more stable than ZSM-5. An optimum of 9.7 was found for pH value leading to formation of ZSM-5 crystals with appropriate crystallinity. The catalytic performance test of the prepared H-ZSM-5 was carried out in fixed-bed reactor at 550°C. The obtained data showed a conversion of 68% for propane while the selectivity towards aromatics was 37%. A gradual decreasing trend in both of the terms was also observed which implies the preferential deactivation of active sites
Keywords:
Authors
Soroush Baradaran
Chemical Engineering Department, Amirkabir University of Technology, Hafez Avenue, Tehran, Iran.
Morteza Sohrabi
Chemical Engineering Department, Amirkabir University of Technology, Hafez Avenue, Tehran, Iran.
Parisa Moghimpour Bijani
Catalyst Research Group, Petrochemical Research and Technology Company, National Petrochemical Company, Tehran, Iran.
Sayed Javid Royaee
Refining Technology Development Division, Research Institute of Petroleum Industry, Tehran,Iran
مراجع و منابع این Paper:
لیست زیر مراجع و منابع استفاده شده در این Paper را نمایش می دهد. این مراجع به صورت کاملا ماشینی و بر اساس هوش مصنوعی استخراج شده اند و لذا ممکن است دارای اشکالاتی باشند که به مرور زمان دقت استخراج این محتوا افزایش می یابد. مراجعی که مقالات مربوط به آنها در سیویلیکا نمایه شده و پیدا شده اند، به خود Paper لینک شده اند :