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Mechanical and Thermal properties of New Polyimide/Nanocomposites Containing Sulfon moiety in the main chain including sulfonic acid-functionalized magnetic nanoparticles

عنوان مقاله: Mechanical and Thermal properties of New Polyimide/Nanocomposites Containing Sulfon moiety in the main chain including sulfonic acid-functionalized magnetic nanoparticles
شناسه ملی مقاله: ICNN05_086
منتشر شده در پنجمین کنگره بین المللی نانو و فناوری نانو (ICNN2014) در سال 1393
مشخصات نویسندگان مقاله:

Mahdi Amini - Organic Polymer Chemistry Research Laboratory, Faculty of science, Department of Chemistry, Arak University,Arak, Iran
Khalil Faghihi - Organic Polymer Chemistry Research Laboratory, Faculty of science, Department of Chemistry, Arak University,Arak, Iran

خلاصه مقاله:
In this work, sulfonic acid-functionalized magnetic nanoparticles (ASA-MNPs) were prepared. Then, a seriesof Nanocomposite consisted of organic polyimide and ASA-MNPs varying from 1 to 3 wt. % were successfully preparedby in situ polymerization. Polyimide used as a matrix of Nanocomposite was prepared through the reaction ofbenzophenone-3,3′,4,4′-tetracarboxylic dianhydride and 3,3´- diamino diphenyl sulfone in N,N-dimethylacetamide(DMAc). The effect of ASA-MNPs on Mechanical and thermal properties of synthesized polyimide will be examined.Results showed that the addition of ASA-MNPs resulted in a substantial increase of the thermal stability and char yieldsof the Nano composites compared to those of the neat PI. Addition of the ASA-MNPs to 1 %( w/w) to polyimide filmssignificantly improved the tensile strength, but as ASA-MNPs concentration increased to 3 %( w/w) to polyimide filmsdecreased the tensile strength.

کلمات کلیدی:
magnetic nanoparticles , Polyimide , Nanocomposite

صفحه اختصاصی مقاله و دریافت فایل کامل: https://civilica.com/doc/397294/