Synthesis of nanoparticles of two organotin(IV) complexes bearing phosphoramide ligands
عنوان مقاله: Synthesis of nanoparticles of two organotin(IV) complexes bearing phosphoramide ligands
شناسه ملی مقاله: ICNN05_301
منتشر شده در پنجمین کنگره بین المللی نانو و فناوری نانو (ICNN2014) در سال 1393
شناسه ملی مقاله: ICNN05_301
منتشر شده در پنجمین کنگره بین المللی نانو و فناوری نانو (ICNN2014) در سال 1393
مشخصات نویسندگان مقاله:
Zahra Shariatinia - Department of Chemistry, Amirkabir University of Technology (Polytechnic), Tehran, Iran
خلاصه مقاله:
Zahra Shariatinia - Department of Chemistry, Amirkabir University of Technology (Polytechnic), Tehran, Iran
Two novel organotin(IV) complexes containing phosphoric triamide ligands were synthesized using ultrasonicmethod and characterized by multinuclear (1H, 31P, 13C) NMR, infrared, ultraviolet and fluorescence spectroscopy as wellas elemental analysis. The 1H NMR spectra of complexes 1 and 2 proved that the Sn atoms adopt octahedral configurations.The nanoparticles of complexes 1 and 2were also prepared by ultrasonic method and their FE-SEM micrographs indicatedidentical spherical morphology with the particles sizes about 20-25 nm. The fluorescence spectra exhibited blue shifts forthe maximum wavelength of emission upon complexation.
کلمات کلیدی: FE-SEM, Nanoparticle, NMR, Ultrasonic method, Fluorescence spectroscopy
صفحه اختصاصی مقاله و دریافت فایل کامل: https://civilica.com/doc/397485/