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Fe3O4/SiO2/(CH2)3N+Me3Br3–catalyzed solvent-free synthesis of five- and six-membered heterocycles

عنوان مقاله: Fe3O4/SiO2/(CH2)3N+Me3Br3–catalyzed solvent-free synthesis of five- and six-membered heterocycles
شناسه ملی مقاله: ICNN05_499
منتشر شده در پنجمین کنگره بین المللی نانو و فناوری نانو (ICNN2014) در سال 1393
مشخصات نویسندگان مقاله:

A Farrokhi - Department of Chemistry, Science and Research Branch, Islamic Azad University, Tehran, Iran
I Yavari - Department of Chemistry, Science and Research Branch, Islamic Azad University, Tehran, Iran
K Ghodrati - Department of Chemistry, Islamic Azad University, Kermanshah Branch, Kermanshah, Iran

خلاصه مقاله:
Functionalized magnetic core–shell nanoparticle [Fe3O4/SiO2/(CH2)3N+Me3Br3-] is prepared by coprecipitationmethod, characterized by transmission electron microscopy, FT-IR, X-ray diffraction, and vibrating samplemagnetometer. The catalytic activity of this nanoparticle was tested in the syntheses of imidazole, benzothiazole, andperimidine derivatives, under solvent-free conditions. The catalyst was readily recycled by the use of an external magneticfield and and could be reused five times without significant loss of activity or mass.

کلمات کلیدی:
Magnetically retrievable; Grafting; Silica; Nano-hybrid; Heterocyclic synthesis

صفحه اختصاصی مقاله و دریافت فایل کامل: https://civilica.com/doc/397677/