Electrocatalytic behavior of modified carbon paste electrode with Ni(ii)-zeolite for oxidation of methanol in a basic solution
عنوان مقاله: Electrocatalytic behavior of modified carbon paste electrode with Ni(ii)-zeolite for oxidation of methanol in a basic solution
شناسه ملی مقاله: JR_SJPAS-3-12_002
منتشر شده در شماره 12 دوره 3 فصل December در سال 1393
شناسه ملی مقاله: JR_SJPAS-3-12_002
منتشر شده در شماره 12 دوره 3 فصل December در سال 1393
مشخصات نویسندگان مقاله:
m Abrishamkar - Department of chemistry, College of Science, Ahvaz branch , Islamic Azad university, Ahvaz, IRAN.Corresponding author; Department of chemistry, College of Science, Ahvaz branch , Islamic Azad university, Ahvaz, Iran.
n Kiamehr - Department of chemistry, College of Science, Ahvaz branch , Islamic Azad university, Ahvaz, IRAN.
خلاصه مقاله:
m Abrishamkar - Department of chemistry, College of Science, Ahvaz branch , Islamic Azad university, Ahvaz, IRAN.Corresponding author; Department of chemistry, College of Science, Ahvaz branch , Islamic Azad university, Ahvaz, Iran.
n Kiamehr - Department of chemistry, College of Science, Ahvaz branch , Islamic Azad university, Ahvaz, IRAN.
In this research, the electrochemical behavior of Ni-zeolite modified carbon paste electrode in the form of Ni/NiZSM-5/CPE and unmodified carbon paste electrode were studied using cyclic voltammetry and chronoamperometric techniques. It was found that methanol was oxidized by NiOOH generated with further electrooxidation of Ni ions which were doped in modified electrode during the anodic sweep. Also, the rate constant for the catalytic reaction (K) of methanol was calculated 2.64* 10⁵cm³s⁻¹mol⁻¹ via Cottrell equation.
کلمات کلیدی: Methanol , Fuel cell , Zeolite , Modified , Electrooxidation
صفحه اختصاصی مقاله و دریافت فایل کامل: https://civilica.com/doc/406263/