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Investigations on the Effect of DMAc and DMF as Plasticizers onto Conductivity of PMMA Based Polymer Electrolyte Membrane

عنوان مقاله: Investigations on the Effect of DMAc and DMF as Plasticizers onto Conductivity of PMMA Based Polymer Electrolyte Membrane
شناسه ملی مقاله: ISPST12_568
منتشر شده در دوازدهمین سمینار بین المللی علوم و تکنولوژی پلیمر در سال 1395
مشخصات نویسندگان مقاله:

Nasim Pourali - M.Sc. student, Department of chemistry Amirkabir University of Technology, Tehran, Iran
Leila Naji - Assistant professor, Department of chemistry, Amirkabir University of Technology, Tehran, Iran
Mohammad Hassan Mousazade - Assistant professor, Department of chemistry, Amirkabir University of Technology, Tehran, Iran
Zahra Fakharan - Ph.D. candidate, Department of chemistry, Amirkabir University of Technology, Tehran, Iran

خلاصه مقاله:
Polymethylmatacrylate (PMMA) is a lightweight thermoplastic polymer host having 96% amorphous content at 25°C. It can absorb much electrolyte leading to Increase its conductivity in order to use as gel polymer electrolyte membrane. To this end, in the present study gel polymer electrolyte membranes containing PMMA, lithium perchlorete (LiClO4) and two different plasticizers dimethylformamide (DMF) and dimethylacetmide (DMAc) were prepared by solution casting method. The comparison between ionic conductivity and morphology of these electrolytes has been studied by electrochemical impedance spectroscopy (EIS) and scanning electron microscopy (SEM). It was observed that polymer electrolyte which prepared with DMAc has smoother surface and shows higher conductivity (30% increment)

کلمات کلیدی:
Polymer membrane- Gel Polymer Electrolyte- Polymethylmetacrylate- Plasticizer, Conductivity

صفحه اختصاصی مقاله و دریافت فایل کامل: https://civilica.com/doc/578455/