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CU(II) COMPLEX OF DENDRITIC AMINO POLYMER AS AN EFFICIENT CATALYST FOR STRECKER REACTION IN MILD CONDITIONS

عنوان مقاله: CU(II) COMPLEX OF DENDRITIC AMINO POLYMER AS AN EFFICIENT CATALYST FOR STRECKER REACTION IN MILD CONDITIONS
شناسه ملی مقاله: TCPCO04_039
منتشر شده در چهارمین همایش ملی شیمی،پتروشیمی و نانو ایران در سال 1395
مشخصات نویسندگان مقاله:

M Kazemnejadi - Department of Chemistry, College of sciences, Shiraz University, Shiraz 71946 84795 Iran
A.R Sardarian - Department of Chemistry, College of sciences, Shiraz University, Shiraz 71946 84795 Iran
H Eslahi - Department of Chemistry, College of sciences, Shiraz University, Shiraz 71946 84795 Iran
M Esmeilpour - Department of Chemistry, College of sciences, Shiraz University, Shiraz 71946 84795 Iran

خلاصه مقاله:
A general method for efficient two steps Strecker reaction of various Schiff base compounds were developed using Cu(II)-Schiff base complex decorated on a dendritic amino polymer as a heterogeneous nano-catalyst. A series of -aminonitriles were obtained in high to excellent yields (81–99%). The transformations occur in water as a solvent at room temperature as a mild and eco-friendly conditions. The nano-catalyst can be simply recovered from the reaction mixture and reused for several times without any significant loss in the activity.

کلمات کلیدی:
Dendrimer, Cooper complex, α-Aminonitriles, Schiff base, Strecker reaction, Heterogeneous catalyst

صفحه اختصاصی مقاله و دریافت فایل کامل: https://civilica.com/doc/587279/