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Performance of Dealuminated Ni/ZSM-5 Catalyst in Dry Reforming of Methane

عنوان مقاله: Performance of Dealuminated Ni/ZSM-5 Catalyst in Dry Reforming of Methane
شناسه ملی مقاله: TCPCO04_111
منتشر شده در چهارمین همایش ملی شیمی،پتروشیمی و نانو ایران در سال 1395
مشخصات نویسندگان مقاله:

Gholamreza Moradi - Catalyst Research Center, Petroleum and Chemical engineering faculty, Razi University, Kermanshah, Iran
Hamed Hemmati - Catalyst Research Center, Petroleum and Chemical engineering faculty, Razi University, Kermanshah, Iran
Gholamreza Abbasi - Catalyst Research Center, Petroleum and Chemical engineering faculty, Razi University, Kermanshah, Iran

خلاصه مقاله:
Ni/ZSM-5 modified Nano catalyst containing 3, 5 and 7wt. % Ni were prepared byimpregnation method for DRM. Dealumination of ZSM-5 carried out by HNO3 solution as adealumination agent. This process led to increase Si/Al ratio for ZSM-5. For approaching to the higherconversion and H2/CO ratio, higher concentration of acid and lower temperature for treatment ofZSM-5 must be used. The sample that was prepared by higher concentration of acid and lowertemperature in dealumination process, with 5%wt Ni showed a better activity and stability thanunmodified sample during DRM at 700°C for 30h time on stream.

کلمات کلیدی:
Catalyst, Dry reforming, Methane, dealumination, Ni/ZSM-5

صفحه اختصاصی مقاله و دریافت فایل کامل: https://civilica.com/doc/587351/