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A Fluorescence Active Catalyst Support Comprising Carbon Quantum Dots and Magnesium Oxide Doping for Stabilization of Palladium Nanoparticles: Application as a Recoverable Catalyst for Suzuki Reaction in Water

عنوان مقاله: A Fluorescence Active Catalyst Support Comprising Carbon Quantum Dots and Magnesium Oxide Doping for Stabilization of Palladium Nanoparticles: Application as a Recoverable Catalyst for Suzuki Reaction in Water
شناسه ملی مقاله: CHCONF04_135
منتشر شده در چهارمین کنفرانس بین المللی نوآوری های اخیر در شیمی و مهندسی شیمی در سال 1396
مشخصات نویسندگان مقاله:

Mohammad Gholinejad - Department of Chemistry, Institute for Advanced Studies in Basic Sciences, Gava Zang, Zanjan ۴۵۱۳۷-۶۶۷۳۱, Iran
Maedeh Bahrami - Department of Chemistry, Institute for Advanced Studies in Basic Sciences (IASBS), P. O. Box ۵۱۹۵-۱۱۵۹, Gava zang, Zanjan ۴۵۱۳۷-۶۷۳۱, Iran
Carmen Najera - bDepartamento de Química Orgánica and Centro de Innovación en Química Avanzada (ORFEO-CINQA). Universidad de Alicante, Apdo. ۹۹, E-۰۳۰۸۰-Alicante, Spain

خلاصه مقاله:
Novel magnesium oxide-carbon quantum dots have been synthesized and used for the formation and stabilization ofpalladium nanoparticles. This highly water dispersible material, Pd@MgO-CQD, has been used as an active catalystfor Suzuki coupling of aryl bromides at room temperature and aryl chlorides at 80 °C in water. Using fluorescenceemission of the material, a new protocol for determine of Pd loading and leaching in catalyst preparation and recyclingprocess was developed.

کلمات کلیدی:
MgO, Carbon, Quantum dots, Fluorescence, Palladium, Suzuki

صفحه اختصاصی مقاله و دریافت فایل کامل: https://civilica.com/doc/675649/