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Dicyanomethane in the Form of a Coordination Polymer

عنوان مقاله: Dicyanomethane in the Form of a Coordination Polymer
شناسه ملی مقاله: CBGCONF04_052
منتشر شده در چهارمین کنفرانس بین المللی پژوهشهای کاربردی در علوم شیمی و زیست شناسی در سال 1396
مشخصات نویسندگان مقاله:

Effat Iravani - Nuclear Material & Fuel Cycle Research School, Nuclear Science & Technology Research Center, Tehran, Iran
Sodeh Sadjadi - Nuclear Material & Fuel Cycle Research School, Nuclear Science & Technology Research Center, Tehran, Iran

خلاصه مقاله:
Dicyanomethane was reacted with tert-butyl arsenic dilithium in a mixture of tetrahydrofuran and trimethyl ethylene diamine. Dicyanomethane was deprotonated leading to the formation of a kind of coordination polymer. The resulted coordination polymer was characterized using NMR- and FT-IR spectroscopy, Mass spectrometry and single crystal structure analysis. According to the result of analysis, the crystallized product contain cations and anions extending in an infinite helix chain along [010].

کلمات کلیدی:
crystal structure, coordination polymer, dicyanomethane

صفحه اختصاصی مقاله و دریافت فایل کامل: https://civilica.com/doc/686159/