Benzonitrile in a Redox Reaction with As-containing Dilithium Salt
عنوان مقاله: Benzonitrile in a Redox Reaction with As-containing Dilithium Salt
شناسه ملی مقاله: CBGCONF04_053
منتشر شده در چهارمین کنفرانس بین المللی پژوهشهای کاربردی در علوم شیمی و زیست شناسی در سال 1396
شناسه ملی مقاله: CBGCONF04_053
منتشر شده در چهارمین کنفرانس بین المللی پژوهشهای کاربردی در علوم شیمی و زیست شناسی در سال 1396
مشخصات نویسندگان مقاله:
Effat Iravani - Nuclear Material & Fuel Cycle Research School, Nuclear Science & Technology Research Center, Tehran, Iran
Sodeh Sadjadi - Nuclear Material & Fuel Cycle Research School, Nuclear Science & Technology Research Center, Tehran, Iran
خلاصه مقاله:
Effat Iravani - Nuclear Material & Fuel Cycle Research School, Nuclear Science & Technology Research Center, Tehran, Iran
Sodeh Sadjadi - Nuclear Material & Fuel Cycle Research School, Nuclear Science & Technology Research Center, Tehran, Iran
Base stable benzonitrile was reacted with tert-butyl arsenic dilithium in tetrahydrofuran. Crystallization of the product was performed in tetramethylethylenediamine and dimethyldiglycol. The resulted aromatic five–membered diaza cycle containing arsenic was coordinated in salt form and characterized using NMR and FT–IR spectroscopy, Mass spectrometry and single crystal structure analysis. According to the result of analysis, the crystallized product consists of distorted octahedrally coordinated Li+ ion, [Li(MeO(CH2)2O(CH2)2OMe)2]+, and the complex anion [Li(Me2N(CH2)2NMe2){As[NC(C6H5)NC(C6H5)]}2]– with a distorted tetrahedrally environment of the Li+ ion.
کلمات کلیدی: crystal structure, aromatization, benzonitrile
صفحه اختصاصی مقاله و دریافت فایل کامل: https://civilica.com/doc/686160/