Nano sphered-shape MgAl2O4: a recyclable, green and efficient catalyst for the one-step synthesis of 1 -aryl-2 -(2-oxoindolin-3- yl)spiro[indoline-3,5 -pyrroline]-2,3 -diones
Publish Year: 1396
نوع سند: مقاله کنفرانسی
زبان: English
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شناسه ملی سند علمی:
CBGCONF04_141
تاریخ نمایه سازی: 22 دی 1396
Abstract:
In this paper, nano MgAl2O4 has been synthesized via a modified co-precipitation route using poly ethylene glycol (PEG) 5000 as an non-ionic surfactant, and characterized by fourier transform infrared spectroscopy (FT-IR), energy-dispersive X-ray spectroscopy (EDX), and scanning electron microscopy (SEM) techniques. The synthesized anocatalyst has been used for the one-pot and one-step condensation of isatins, arylamines, and acetone. The desired 1 -aryl-2 -(2-oxoindolin-3-yl)spiro[indoline-3,5 -pyrroline]-2,3 -diones has been prepared in excellent yields using an easily to handle, non-toxic, inexpensive, and non-moisture sensitive nano reagent. The reaction proceeded well undersolvent-free conditions to avoid hazardous solvent usage. The reusability of the recovered nanosphered-shape MgAl2O4 has been performed during four run without activity loss
Keywords:
MgAl2O4 , Spiro compounds , .One-pot reaction , .Multi-component reaction , .Metallic oxide nano particles
Authors
Zahra Khademi
Department of Chemistry, Faculty of Physics and Chemistry, Alzahra University, Tehran, Iran
Kobra Nikoofar
Department of Chemistry, Faculty of Physics and Chemistry, Alzahra University, Tehran, Iran