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Hydrogen production by steam reforming of dimethyl ether over Cu/ZnO/Al2O3 and H-ZSM-5 catalysts: An experimental and modeling study

عنوان مقاله: Hydrogen production by steam reforming of dimethyl ether over Cu/ZnO/Al2O3 and H-ZSM-5 catalysts: An experimental and modeling study
شناسه ملی مقاله: JR_IJHFC-1-3_003
منتشر شده در شماره 3 دوره 1 فصل Summer در سال 1393
مشخصات نویسندگان مقاله:

Paria Amirshaghaghi - Chemical Engineering Department, Babol University of Technology, P.O. Box ۴۸۴, ۴۷۱۴۸۷۱۱۶۷ Babol, Iran
Ali Eliassi - Chemical Technologies Research Department, Iranian Research Organization for Science and Technology (IROST), Tehran, Iran
Majid Taghizadeh - Chemical Engineering Department, Babol University of Technology, P.O. Box ۴۸۴, ۴۷۱۴۸۷۱۱۶۷ Babol, Iran

خلاصه مقاله:
Hydrogen was produced by steam reforming of dimethyl ether (DME) using a physical mixture of commercial HZSM-5 zeolite (for DME hydrolyzing) and Cu/ZnO/ Al2O3 (for methanol steam reforming) as a catalyst in a fixed bed reactor. The experiments were performed at atmospheric pressure and in a temperature range from 270 to 310 °C. The effects of feed temperature and gas hourly space velocity (GHSV) between 2420 and 4615 h−1 on DME conversion and H2 and CO concentrations in the gas-phase products were investigated. In addition, the temperature changes along the catalyst bed were measured. The results showed that DME conversion increased with increasing temperature, and also, DME conversion decreased with increasing GHSV. Finally, a homogeneous one-dimensional model was used to model the reactor of hydrogen production by steam reforming of DME. The predicted temperature profile along the catalyst bed and conversion were compared with the experimental data. Themodel results and experimental data were found to be in good agreement.

کلمات کلیدی:
Dimethyl Ether,Hydrogen production,Steam Reforming,Modeling,Fixed Bed Reactors

صفحه اختصاصی مقاله و دریافت فایل کامل: https://civilica.com/doc/704876/