New Coated Graphite Potentiometric Sensor based on benzo-18-crown-6
عنوان مقاله: New Coated Graphite Potentiometric Sensor based on benzo-18-crown-6
شناسه ملی مقاله: ISPTC20_262
منتشر شده در بیستمین کنفرانس شیمی فیزیک ایران (IPCC۲۰) در سال 1396
شناسه ملی مقاله: ISPTC20_262
منتشر شده در بیستمین کنفرانس شیمی فیزیک ایران (IPCC۲۰) در سال 1396
مشخصات نویسندگان مقاله:
Sh Lovineh - Department of Chemistry, khouzestan Science and Research Branch, Islamic Azad University, Ahvaz, Iran- Department of chemistry, Ahvaz Branch, Islamic Azad University, Ahvaz, Iran
خلاصه مقاله:
Sh Lovineh - Department of Chemistry, khouzestan Science and Research Branch, Islamic Azad University, Ahvaz, Iran- Department of chemistry, Ahvaz Branch, Islamic Azad University, Ahvaz, Iran
In this project, a highly selective calcium coated graphite electrode was prepared by benzo-18-crown-6 as an ionophore into plasticized polyvinylchloride (PVC) membrane. The best response characteristic was observed using the membrane composition of dioctyl phthalate (DOP) = 63.0 mg, PVC = 30.0 mg, sodiumtetraphenylborate (NaTPB) = 3.0 mg and benzo-18-crown-6 = 4.0 mg. The electrode has a fast response time of 10 s, with a satisfactory reproducibility and relatively long life time of 28 days without significant drift in potential. This electrode reveals a very good selectivity toward Ca2+ ion over a wide range of alkali, transition and heavy metal cations.
کلمات کلیدی: Calcium (II) cation, Ion selective electrode, Potentiometry
صفحه اختصاصی مقاله و دریافت فایل کامل: https://civilica.com/doc/741992/