A highly efficient oxidation of cyclohexane over VPO catalysts using tert-Butyl hydroperoxide
عنوان مقاله: A highly efficient oxidation of cyclohexane over VPO catalysts using tert-Butyl hydroperoxide
شناسه ملی مقاله: ISPTC20_293
منتشر شده در بیستمین کنفرانس شیمی فیزیک ایران (IPCC۲۰) در سال 1396
شناسه ملی مقاله: ISPTC20_293
منتشر شده در بیستمین کنفرانس شیمی فیزیک ایران (IPCC۲۰) در سال 1396
مشخصات نویسندگان مقاله:
M.H Farghadani - Department of arak University, Arak, ۳۸۱۵۶ ۸۷۹, Iran
V Mahdavi - Department of arak University, Arak, ۳۸۱۵۶ ۸۷۹, Iran
خلاصه مقاله:
M.H Farghadani - Department of arak University, Arak, ۳۸۱۵۶ ۸۷۹, Iran
V Mahdavi - Department of arak University, Arak, ۳۸۱۵۶ ۸۷۹, Iran
A highly efficient oxidation of cyclohexane to cyclohexanol and cyclohexanone is accomplished overcalcined vanadium phosphorus oxide (VPO) catalysts in a relatively mild condition using tert-Butyl hydroperoxideunder a atmosphere condition. This heterogeneous catalyst at the end of the reaction is easily separated by the least costof the product. This reaction is investigated in a polar and nonpolar solvent with different dielectric constant. Aftercatalytic tests and determining the best catalyst ,detection and analysis will be done by analyzing XRD, SEM, TGA, IR,.... The activity and selectivity of vanadium phosphate (VPO) catalysts on the mesoporous KIT-6 support for greenoxidation of cyclohexane to cyclohexanone and cyclohexanol were studied using H2O2.
کلمات کلیدی: Cyclohexane ; VPO Catalyst ; TBHP ; Oxidation ; Acetonitrile
صفحه اختصاصی مقاله و دریافت فایل کامل: https://civilica.com/doc/742023/