Adsorption and neutralization chemistry of dimethyl methyl phosphonate (DMMP) as an organo-phosphorous pollutant (OPP) on the surface of nano-structured Co3O4 and MnCo2O4 catalysts

In this work, the practicality of catalytic surfaces of nano-structured Co3O4 and MnCo2O4 for theadsorption and neutralization reactions of dimethyl methyl phosphonate (DMMP) as a toxicagricultural organo-phosphorous pesticide has been investigated. The Co3O4 and MnCo2O4 NPshave been successfully prepared by precipitation method using cobalt nitrate and manganesenitrate as the precursors and then characterized by SEM-EDX and XRD. The application of thesynthesized nanoparticles as solid catalysts for the adsorption and neutralization of dimethylmethyl phosphonate (DMMP) was assayed in different solvents and monitored by 31PNMR andIR analyses. The experimental results have shown that 39%, 47% and 62% of DMMP have beenadsorbed on the surface of Co3O4 nanoparticles in isopropanol, chloroform and decane solventsafter 5 h, respectively. While, higher amounts (80%, 92% and 100%) were removed in the samesolvents respectively, MnCo2O4 nanoparticles were chosen as the catalytic surface. Thisdemonstrates that the choice of nanoparticle and solvent (MnCo2O4 nanoparticles and decane)have a great impact on the neutralization of DMMP.

Keywords:

Co3O4 , MnCo2O4 , nanoparticles , precipitation , dimethyl methyl phosphonate (DMMP) , adsorption , neutralization