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Determination of solubilities of cinnamic acid, phenoxyacetic acid and 4- methoxyphenylacetic acid in Sc-CO2 using three mixing rules

Publish place: 06th International Congress on Chemical Engineering
Publish Year: 1388
نوع سند: مقاله کنفرانسی
زبان: English
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https://civilica.com/doc/77370

شناسه ملی سند علمی:

ICHEC06_095

تاریخ نمایه سازی: 1 مهر 1388

Abstract:

The Peng-Robinson (PR) equation of state (EOS) and three different mixing rules including van der Waals one fluid, Ried & Panagiotopoulos and Kwak & Mansoori mixing rules are used to calculate the solubilities of cinnamic acid, phenoxyacetic acid and 4-methoxyphenylaceticacid insupercritical carbon dioxide at 308.2 to 328.2K. The results showed that the Ried & Panagiotopoulos and Kwak & Mansoori mixing rules have good agreement with experimental data. The results demonstrate that the mixing rule selection plays an important role on solubility calculations using EOS.

Keywords:

Peng-Robinson equation of state , Mixing rules , Solid solubility , Supercritical carbon dioxide

Authors

HamidReza Satvati

M.S. Student of School of Chemical, Gas and Petroleum Engineering, Semnan University, Semnan, Iran.

Mohammad Nader Lotfollahi

School of Chemical, Gas and Petroleum Engineering, Semnan University, Semnan, Iran.

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